Trace Elements in West Virginia Coals
Lanthanum (La) Summary Statistics
Whole coal lanthanum averaged 9.23 ppm (± 5.88 ppm) in West
Virginia coals with a histogram showing a distribution skewed toward lower
values with a significant tail of higher values and a maximum of 54 ppm
in a bench of the Coalburg coal. Lanthanum correlated slightly with
ash yield, but mainly with rare earth elements occurring in the mineral
monazite,
especially cerium (Ce) and lower for samarium
(Sm), europium (Eu), lutetium (Lu), ytterbium (Yb), neodymium (Nd) and
terbium (Tb). Lanthanum also correlated with ash related elements
thorium (Th), chromium (Cr), hafnium (Hf), scandium (Sc), tantalum (Ta),
lithium (Li), lead (Pb) and vanadium (V).
Spearman Correlation Coefficients (r) with Lanthanum
Ash Yield
|
Ce
|
Sm
|
Th
|
Eu
|
Cr
|
Hf
|
Sc
|
+0.6738
|
+0.9569
|
+0.9010
|
+0.8745
|
+0.8307
|
+0.8179
|
+0.7947
|
+0.7672
|
n = 545
|
n = 540
|
n = 536
|
n = 526
|
n = 534
|
n = 544
|
n = 504
|
n = 545
|
Ta
|
Li
|
Pb
|
Lu
|
Yb
|
V
|
Nd
|
Tb
|
+0.7487
|
+0.7592
|
+0.7149
|
+0.7105
|
+0.7100
|
+0.6841
|
+0.6794
|
+0.6784
|
n = 536
|
n = 545
|
n = 542
|
n = 503
|
n = 544
|
n = 544
|
n = 415
|
n = 488
|
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