Trace Elements in West Virginia Coals
Lutetium
(Lu) Summary Statistics
Lutetium in West Virginia coals averaged 0.133 ppm (± 0.073
ppm) with a histogram showing a near normal distribution with a significant
tail of samples toward higher values. Highest Lu values occurred
in coals of the upper Kanawha Formation and Allegheny Group (No. 2 Gas,
Stockton, Coalburg and Winifrede coals). The maximum Lu value was 0.57
ppm in a bench of the Coalburg coal. Lutetium correlated very poorly
with ash yield, and correlated somewhat with ash related elements such
as scandium (Sc), thorium (Th), chromium (Cr), lead (Pb), vanadium (V),
gallium (Ga), tantalum (Ta), hafnium (Hf) and lithium (Li). Lutetium
correlated highly with rare earth elements such as ytterbium (Yb), samarium
(Sm), europium (Eu), terbium (Tb) and erbium (Er) and components of monazite,
especially cerium (Ce), yttrium (Y) and lanthanum (La).
Spearman Correlation Coefficients (r) with Lutetium
Ash Yield
|
Yb
|
Sm
|
Sc
|
Eu
|
Tb
|
Th
|
Cr
|
Pb
|
+0.5863
|
+0.9324
|
+0.8589
|
+0.8488
|
+0.8343
|
+0.7792
|
+0.7614
|
+0.7349
|
+0.7286
|
n = 503
|
n = 502
|
n = 503
|
n = 503
|
n = 501
|
n = 537
|
n = 486
|
n = 502
|
n = 500
|
Ce
|
Y
|
La
|
V
|
Ga
|
Ta
|
Hf
|
Li
|
Er
|
+0.7278
|
+0.7111
|
+0.7105
|
+0.7068
|
+0.6757
|
+0.6438
|
+0.6288
|
+0.6277
|
+0.6080
|
n = 503
|
n = 503
|
n = 503
|
n = 502
|
n = 502
|
n = 456
|
n = 502
|
n = 503
|
n = 178
|
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