Trace Elements in West Virginia Coals
Rubidium
(Rb) Summary Statistics
Rubidium shows a histogram skewed to lower values with a significant
tail of higher values and a mean whole coal Rb of 23.62 ppm (± 21.13
ppm) in West Virginia coals. A maximum value of 161.0 ppm was found
in a bench of the Stockton coal. Rubidium correlated moderately with
ash yield, very highly with cesium (Cs), and moderately to slightly with
ash related elements such as chromium (Cr), vanadium (V), scandium (Sc),
samarium (Sm), gallium (Ga), thorium (Th), tellurium (Te) and lithium (Li).
Rubidium also slightly correlated with rare earth elements present in monazite,
especially cerium (Ce), lanthanum (La) and lutetium (Lu). The high
correlation with Cs is suspect, but Cs is known to occur in nature in close
association with Rb because of their similar atomic radii, for example
in the mineral pollucite (CsAlSi2O6) which has never
been documented in coal, but these two elements most likely substitute
for potassium (K) in clay minerals.
Spearman Correlation Coefficients (r) with Rubidium
Ash Yield
|
Cs
|
Cr
|
V
|
Sc
|
Sm
|
Ga
|
Th
|
Te
|
Lu
|
Ce
|
Li
|
La
|
+0.7473
|
+0.9135
|
+0.6817
|
+0.6552
|
+0.6546
|
+0.6373
|
+0.6265
|
+0.6204
|
+0.6143
|
+0.6090
|
+0.6087
|
+0.6056
|
+0.6029
|
n = 403
|
n = 403
|
n = 403
|
n = 403
|
n = 403
|
n = 120
|
n = 403
|
n = 399
|
n = 105
|
n = 120
|
n =120
|
n = 403
|
n = 120
|



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